A novel 3-D cuprous iodide polymer with a high Cu/I ratio.
نویسندگان
چکیده
A novel 3-D cuprous iodide polymer [CuI(μ6-L)]n with a Cu/I ratio as high as 3 (1, H2L = 1,3-bis(2H-tetrazol-5-yl)benzene) has been hydrothermally synthesized. The 3-D framework of 1 is constructed by the linkages of rare 1-D cationic aggregates [CuI2+]n and anionic bi-tetrazolate bridges. 1 shows unusually thermochromic luminescent and photocatalytic properties, and its density functional theory calculation has also been studied.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 47 10 شماره
صفحات -
تاریخ انتشار 2018